Material name: CTF-1
Other name: CTF-HUST-1
CAS: 2155822-92-5 or 2173362-13-3
Structure information
Unit molecular formula C8H10N4.C8H6O2 Unit molecular weight 296.32384
Monomer
Benzene-1,4-dicarboximidamide dihydrochloride CAS: 14401-56-0;
Terephthalaldehyde 1,4-Phthalaldehyde CAS: 623-27-8
Pore diameter 1.2nm Pore volume 0.4 cm3/g
Specific surface BET specific surface 520m2/g
Analog structure
Product traits
Product appearance
Yellow powder
Yellowish powders
Particle size
stability
1) CTF has extremely stable properties and is one of the most stable COF materials. Water and acid and alkali resistant.
2) Thermal decomposition temperature is greater than 400 degrees
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) 150 degrees vacuum activation for 2 hours before use
Other features
Fluorescence: NA
Application field
1) For gas and pollutant adsorption
2) Good pores can be used to support other catalysts
3) Good photocatalytic hydrolysis hydrogen production performance
Characterization map
references
1) P. Kuhn, M. Antonietti, A. Thomas, Angew. Chem. Int. Ed. 2008, 47, 3450–3453, DOI: 10.1002/anie.200705710; Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis
2) M. Liu, Q. Huang, S. Wang, Z. Li, B. Li, S. Jin, B. Tan, Angew. Chem. Int. Ed. 2018, 57, 11968–11972, DOI: 10.1002/ anie.201806664; Crystalline Covalent Triazine Frameworks by In Situ Oxidation of Alcohols to Aldehyde Monomers
3) M. Liu, K. Jiang, X. Ding, S. Wang, C. Zhang, J. Liu, Z. Zhan, G. Cheng, B. Li, H. Chen, S. Jin, B. Tan, Adv. Mater. 2019, 31, 1807865, DOI: 10.1002/adma.201807865; Controlling Monomer Feeding Rate to Achieve Highly Crystalline Covalent Triazine Frameworks
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